The short answer? Yes, you can. The long answer? It depends on your tariff and energy provider.
Most electric vehicle deals are only available to existing customers of that company, but you may still be able to get one with a different provider by jumping through some extra hoops.
If you are already an existing customer, switching to a different EV tariff should be simple, as you can just call your provider up and they will start the switching process for you.
However, its worth knowing that to switch to an EV tariff you will need to have a smart meter installed, if you haven't done so already.
If you are not an existing customer, there are a few extra steps involved.
You will need to switch to the energy provider first before you are able to take up an EV contract. Make sure you opt for their cheapest energy deal when you do, as it could take a number of weeks to make the switch.
Once you've made the switch, you should be able to ask your provider to begin the process of moving you to an EV tariff, but only after the contracted start date.
However, many providers are not taking on new customers at the moment, so it may be difficult to switch. The situation changes regularly though, so it is worth contacting your ideal provider to discuss the options for switching.